hard · Enhanced ACT science

Students dissolved a fixed mass of KNO_3 in 100 g of water and recorded the maximum amount that would dissolve (solubility) at several temperatures:

| Temp (^circC) | Solubility (g per 100 g water) |

| :--- | :--- |

| 20 | 32 |

| 30 | 46 |

| 40 | 64 |

| 50 | 85 |

| 60 | 110 |

A separate sample held 75 g of KNO_3 dissolved in 100 g of water.

As this sample is slowly cooled from 60 ^circC, at approximately what temperature will the first solid crystals begin to form?

  1. Just below 60 ^circC, because 75 g already exceeds the 60 ^circC solubility
  2. Between 40 ^circC and 50 ^circC
  3. Below 20 ^circC, since 75 g stays fully dissolved at every listed temperature
  4. Exactly 30 ^circC, where solubility is 46 g

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