medium · MCAT chem-phys

A 1.0 L saturated solution of AgBr (K_sp = 5.0 × 10^-13) is prepared.

If 0.01 moles of solid NaBr are added, which statement accurately describes the change in molar solubility of AgBr?

  1. The molar solubility remains unchanged because K_sp is a constant.
  2. The molar solubility decreases because the increased [Br^-] drives the dissolution equilibrium toward the solid phase.
  3. The molar solubility increases because the Na^+ ions help stabilize the Ag^+ ions in solution.
  4. The molar solubility increases as the reaction quotient Q becomes less than K_sp.

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