medium · MCAT chem-phys

An organic chemist attempts to separate a mixture of a carboxylic acid and a phenol using extraction.

If the mixture is dissolved in an organic solvent and shaken with an aqueous solution of NaHCO_3 (a weak base), which species will move into the aqueous layer?

  1. Only the phenol, because its aromatic ring makes it more polar.
  2. Both the carboxylic acid and the phenol will move to the aqueous layer.
  3. Only the carboxylic acid, as it is acidic enough to be deprotonated by NaHCO_3.
  4. Neither compound will move, as both are primarily soluble in organic solvents.

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