medium · MCAT chem-phys

A chemist observes that increasing the temperature of a reaction from 300 K to 310 K doubles the rate constant.

Which underlying principle best explains this observation?

  1. The reaction becomes more exothermic at higher temperatures, driving the rate.
  2. The activation energy of the reaction decreases as temperature increases.
  3. A larger fraction of molecular collisions exceed the activation energy at higher temperatures.
  4. The increase in collision frequency alone accounts for the doubling of the rate.

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