medium · MCAT chem-phys

A chemist observes that increasing the temperature of a reaction from 300 K to 310 K doubles the rate constant.

Which underlying principle best explains this observation?

  1. The reaction becomes significantly more exothermic at higher temperatures, driving the rate
  2. The activation energy required for the reaction gradually decreases as the temperature is increased
  3. A larger fraction of molecular collisions exceed the activation energy at higher temperatures.
  4. The increase in the frequency of molecular collisions alone fully accounts for the doubling of the rate

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